Diels-Alder reactions of 12-hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione.

نویسندگان

  • George Majetich
  • Yong Zhang
  • Xinrong Tian
  • Ge Zou
  • Yang Li
  • Yangyang Wang
  • Shougang Hu
  • Eric Huddleston
چکیده

12-Hydroxy-9(10-->20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.

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عنوان ژورنال:
  • Molecules

دوره 18 6  شماره 

صفحات  -

تاریخ انتشار 2013